One widely used approximation method is the Hartree-Fock method. It is based on the rather natural approximation that every electron moves in the potential created by the nucleus plus the average potential of all the other electrons. This assumption leads to the independent-particle model, which essentially reduces the many-electron problem to the problem of solving a number of coupled single-electron equations.
The single-electron equations are solved in an iterative manner until a chosen level of self-consistent accuracy is achieved. Hartree made the first calculation based on these ideas by hand in 1928, but calculations of this type are, of course, best suited for computers. Today there are several computer codes available for anyone who is interested in atomic properties. This outline describes one of the first such codes, written by Herman and Skillman in 1961.
The Hartree-Fock approximation is a fast and reliable method for a wide range of atomic systems, but it is just a FIRST approximation. There are several calculation schemes developed to generate improved results.
Created: November 12, 1998 --- Last Updated: November 28, 2001
By Mark D. Pauli
Partially adapted from Eva Lindroth, Stockholm November 1995